Product ID:02102, FORMULASHELL REGULAR GASOLINE (SUPDAT)
MSDS Date:01/25/1996
FSC:9130
NIIN:00N084621
MSDS Number: CGTNV

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

ALKANES, CYCLOALKANES, ALKENES AND AROMATIC HYDROCARBONS

RTECS: 9999999ZZ

Fraction By Weight: BALANCE

OSHA PEL N/K

ACGIH TLV: N/K

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA 313) (CERCLA)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0-4%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEXANE (N-HEXANE) (CERCLA)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight:

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

1,2,4-TRIMETHYLBENZENE (SARA 313)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

CYCLOHEXANE (SARA 313) (CERCLA)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 0-1%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA 313)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0-3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NAPHTHALENE (SARA 313) (CERCLA)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 0-1%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

AVOIDED AS EVEN SM QTYS MAY RSLT IN ASPIR PNEUM.

RTECS: 9999999ZZ

& RPTD EXPOS MAY PRDCE LIVER DMG. SIGNS & SYMPS

RTECS: 9999999ZZ

EVID BY GIDD, HDCH, DIZZ & NAUS; IN EXTREME CASES,

RTECS: 9999999ZZ

COUGH, LABORED BRTHG & CYANOSIS(BLUISH SKIN); IN

RTECS: 9999999ZZ

CHANGES IN URINE OUTPUT, URINE APPEAR/EDEMA(SWELL

RTECS: 9999999ZZ

OF APPETITE, JAUNDICE(YELLOWISH SKIN COLOR) &

RTECS: 9999999ZZ

IARC HAS DETERM GASOLINE IS POSS CARCIN TO

RTECS: 9999999ZZ

GASOLINE, HAS PRDCED KIDNEY & LIVER CANCERS IN SOME

RTECS: 9999999ZZ

EXPOS TO ETHANOL MAY RSLT IN MULTIPLE ORGAN DMG

RTECS: 9999999ZZ

RPTD TO CAUSE BIRTH DEFECTS IN SOME INFANTS. IARC

RTECS: 9999999ZZ

SHOWN TO CAUSE CANCER IN LAB ANIMALS. SUPPLEMENTAL

RTECS: 9999999ZZ

SPONT KEEP HEAD BELOW HIPS TO PVNT ASPIR OF

RTECS: 9999999ZZ

FOR MORE SPECIFIC INFORMATION CONT NEHC .

RTECS: 9999999ZZ

BE USEFUL IN SUPPRESSING VAP CLOUD; CNTN

RTECS: 9999999ZZ

STATIC BUILDUP, PLACE APPRVD CNTNR ON GROUND.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL,RAT) >5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TOLUENE APPEARS ON NAVY LISTING OF
OCCUP CHEM REPROD HAZARDS. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HNDLG &
EXPOS INFO . ACUTE: EYE CONT: IRR ITATING. SKIN: PRLNGD & RPTD LIQ
CONT CAN CAUSE DEFAT & DRYING OF SKIN RSLTING IN SKIN IRRIT & DERM.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: IARC MONO, SUPP, VOL 7, PG 120,
1987: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE
CARCIN.(SUPDAT)
Effects of Overexposure:HLTH HAZ: INHAL: MAY CAUSE IRRIT TO NOSE,
THROAT & RESP TRACT & ADDNLY, MAY PRDCE LIVER & KIDNEY DMG. HIGH
VAP CONCS MAY PRDCE CNS DEPRESS. PRLNGD & RPTD EXPOS TO BENZENE MAY
CAUSE SERIOUS INJURY TO B LOOD FORMING ORGANS & IS LINKED TO LATER
DEVELOPMENT OF ACUTE MYELOGENOUS LEUKEMIA. INGEST: MAY BE HARMFUL
OR (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, &
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOS TO THIS PROD.
IMPAIRED LIVER & KIDNEY FUNCTION(S) FROM PREEXISTING DISORDERS MAY
BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.

First Aid:EYE: FLUSH W/WATER FOR @ LST 15 MINS WHILE HOLDING EYELIDS
OPEN. GET MED ATTN. SKIN: FLUSH W/WATER WHILE REMOVING CONTAMD
CLTHG & SHOES. FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE
CLTHG/SHOES UNTI L CLEANED. IF IRRIT PERSISTS, GET MED ATTN. INHAL:
REMOVE TO FRESH AIR & PROVIDE OXYG IF BRTHG IS DFCLT. GIVE ARTF
RESP IF NOT BRTHG. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT. IF
VOMIT OCCURS(ING 22)

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3%
Upper Limits:7.6%
Extinguishing Media:WATER FOG, FOAM, DRY CHEM/CO*2. DO NOT USE DIRECT
STREAM OF WATER. PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF
WATER.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . DANGER.
EXTREMELY FLAMM. CLEAR FIRE AREA OF UNPROTECTED PERS & ISOLATE.
COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR ACCUM IN LOW AREAS &
TRAVELING ALONG GROUND AWAY FROM HNDLG SITE. DO NOT WELD,
HEAT/DRILL ON/NEAR CNTNRS. HOWERVER, IF EMER SITUATIONS (SUPDAT)

Spill Release Procedures:ELIM ALL IGNIT SOURCES. HNDLG EQUIP MUST BE
GROUNDED TO PVNT SPK. LG SPILL: ISOLATE HAZ AREA & DENY ENTRY TO
UNNEC PERS. WEAR APPROP NIOSH APPRVD RESP & PROT CLTHG. SHUT OFF
SOURCE OF LEAK ONLY IF SAF E TO DO SO. DIKE & CNTN. WATER FOG MAY
(ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID HEAT, SPK, OPEN FLAME, INCL
PILOT LIGHTS, & STRONG OXIDIZING AGENTS. USE EXPLOSION-PROOF VENT
TO PVNT VAP ACCUM. HARMFUL/FATAL IF SWALLOWED.
Other Precautions:ALL HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING. DO
NOT SIPHON GASOLINE BY MOUTH. WARNING: FLOW OF GASOLINE THRU PUMP
NOZZ CAN PRDCE STATIC ELEC, WHICH MAY CAUSE FIRE IF GASOLINE IS
PUMPED INTO UNGR OUNDED GASOLINE CNTNR. TO AVOID (ING 25)

Respiratory Protection:AVOID BRTHG VAP. UNDER CNDTNS OF POTNTL HIGH
EXPOS, USE OF NIOSH APPRVD RESP IS REC. PER 29CFR 1910.134/29CFR
1910.1028 USE EITHER NIOSH APPRVD ATMMOSPHERE-SUPPLYING
RESP/AIR-PURIFYING RESP FOR ORGANI C VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:NITRILE RUBB, PVA, VITON/NEOPRENE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . CLTHG
PROVIDED BY NITRILE RUBB, POLYVINYL ALCOHOL OR VITON/NEOPRENE.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMKNG/USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG BEFORE REUSE.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: WITH ETHANOL (CONVENTIONAL AND RFG). SPEC GRAV:
0.72-0.76 (H*2O=1). EXPLO HAZ: REQ DRILLING, ONLY TRAINED EMER PERS
SHOULD DRILL. EXPLAN OF CARCIN: OSHA REGULATED:CFR 29 1910.1 028.
EFTS OF OVEREXP: FATAL IF SWALLOWED. INGEST MAY RSLT IN VOMIT;
ASPIR (BRTHG) OF VOMITUS INTO LUNGS MUST BE (ING 11)

Boiling Pt:B.P. Text:>100F,>38C
Vapor Pres:7-14.5 PSI
Vapor Density:3.5
Spec Gravity:SUPDAT
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE COLOR; CLEAR AND BRIGHT LIQUID. HYDROCARBON
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID HEAT, SPARKS, OPEN FLAMES AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES AND STRONG
OXIDIZING AGENTS. PREVENT VAPOR ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE & OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.

Waste Disposal Methods:UNDER EPA -RCRA (40 CFR 261.21). IF THIS PROD
BECOMES WASTE MATL, IT WOULD BE IGNITABLE HAZ WASTE, HAZ WASTE
NUMBER D001. REFER TO LATEST EPA FEDERAL, STATE OR LOCAL REGS
REGARDING PROPER DISP. FOR MO RE SPECIFIC INFORMATION CONT NEHC .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.